HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ammonium Chloride → 5-Amidino-1-tetralone hydrochloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ammonium Chloride | HCID 25517 | — |
| Reactant | Triethyloxonium tetrafluoroborate | HCID 2723982 | — |
| Reactant | 5-Thiocarbamoyl-1-tetralone | HCID 18937923 | — |
| Product | 5-Amidino-1-tetralone hydrochloride | HCID 18937912 | — |
Reaction Steps
Analogously to Example 29b), 8.6 g (42 mmol) of 5-thiocarbamoyl-1-tetralone are treated with 8.8 g (44 mmol) of triethyloxonium tetrafluoroborate and 2.6 g (49 mmol) of ammonium chloride. There is thus obtained the title compound in the form of slightly pink-colored crystals, MS (FAB): (M+H)+ =189.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05840911 |
| Source dataset | uspto-grants-1998_11 |
| ORD ID | ord-bccd037b17414cae8928600923d6d57f |
| Source note | uspto-grants-1998_11 |