Jones' reagent → HCID 178444468, compound

HRID 35792Notes

Reaction equation

HRID 35792 reaction equation
[CH2:1]([C@H:6]1[CH2:11][CH2:10][C@H:9](/[CH:12]=[CH:13]/[CH2:14][O:15][C:16]2[CH:23]=[CH:22][C:19]([CH:20]=[O:21])=[CH:18][CH:17]=2)[CH2:8][CH2:7]1)[CH2:2][CH2:3][CH2:4][CH3:5].CC(C)=[O:26].OS(O)(=O)=O.O=[Cr](=O)=O>CC(C)=O>[CH2:1]([C@H:6]1[CH2:11][CH2:10][C@H:9](/[CH:12]=[CH:13]/[CH2:14][O:15][C:16]2[CH:17]=[CH:18][C:19]([C:20]([OH:26])=[O:21])=[CH:22][CH:23]=2)[CH2:8][CH2:7]1)[CH2:2][CH2:3][CH2:4][CH3:5]

Participants

4

Reactant 2

HCID 131709961Jones' reagentHCID 178444466HCID 178444466, compound

Product 1

HCID 178444468HCID 178444468, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

4.0 g of 4-[(E)-3-(trans-4-pentylcyclohexyl)allyloxy]benzaldehyde, 10 ml of Jones' reagent and 100 ml of acetone were reacted in an analogous manner to Example 2(b) to give 2.6 g of 4-[(E)-3-(trans-4-pentylcyclohexyl)allyloxy]benzoic acid with m.p. 215° C.

Sources & evidence

ORD record
ord-d81b3ea861394a66a770fe1c5592ef49
Source dataset
uspto-grants-1995_05
Patent number
US05411676

Reaction notes

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