HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-alpha-D-glucopyranosyl chloride → 1-(4-nitrobenzyl)-4-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-beta-D-glucopyranosyl)oxy-1H-imidazole-5-carboxamide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-alpha-D-glucopyranosyl chloride | HCID 11100622 | — |
| Reactant | HCID 178513772 | HCID 178513772 | — |
| Product | 1-(4-nitrobenzyl)-4-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-beta-D-glucopyranosyl)oxy-1H-imidazole-5-carboxamide | HCID 13271644 | 33.8% |
Reaction Steps
Following a procedure similar to that of Example 1 but using 1.311 g of 5-carbamoyl-1-(4-nitrobenzyl)imidazolium-4-olate and 3.658 g of 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-α-D-glucopyranosyl chloride there was obtained 1.0 g of 1-(4-nitrobenzyl)-4-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)oxy-1H-imidazole-5-carboxamide.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04464531 |
| Source dataset | uspto-grants-1984_08 |
| ORD ID | ord-79cdc8de2ef942c0b40668274941ce48 |
| Source note | uspto-grants-1984_08 |