HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Methyl-6-methylene-7-octen-2-ol → 2,6,6-Trimethyl-2-vinyltetrahydropyran
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Methyl-6-methylene-7-octen-2-ol | HCID 10975 | — |
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | HCID 6430998 | HCID 6430998 | — |
| Product | 2,6,6-Trimethyl-2-vinyltetrahydropyran | HCID 522514 | 11.7% |
Reaction Steps
Example 12 was repeated except that only 0.105 g triphenylphosphine was used and 22.6 g of N,N-diethyl-7-hydroxygeranylamine was used as the amine. After 9 hours at 120° there was obtained a yield of 11.7% 2,6,6-trimethyl-2-vinyltetrahydropyran, 29.6% myrcenol, 22.2% cis and 17.3% trans-ocimenol.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04467118 |
| Source dataset | uspto-grants-1984_08 |
| ORD ID | ord-9caecc1f57d44f2799fa1adb6dd0ad5b |
| Source note | uspto-grants-1984_08 |