HuagongsheHuagongshe Chemistry Print Report · For research reference only
Myrcenol → 2,6,6-Trimethyl-2-vinyltetrahydropyran
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Myrcenol | HCID 10975 | — |
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | HCID 6430998 | HCID 6430998 | — |
| Reactant | (5Z)-2,6-Dimethyl-5,7-octadien-2-ol | HCID 13547825 | — |
| Product | 2,6,6-Trimethyl-2-vinyltetrahydropyran | HCID 522514 | 13.1% |
Reaction Steps
Example 13 was repeated except that 0.210 g triphenylphosphine was used and 22.6 g N,N-diethyl-7-hydroxynerylamine. After 171/2 hours at 120° C. there was obtained a yield of 13.1% 2,6,6-trimethyl-2-vinyltetrahydropyran, 28.6% myrcenol, 16.1% cis-ocimenol, 21.9% trans-ocimenol.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04467118 |
| Source dataset | uspto-grants-1984_08 |
| ORD ID | ord-3b49818c71524a84a86a8dab25ca3cd1 |
| Source note | uspto-grants-1984_08 |