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Ethyl 4,6,6-trichloro-3,3-dimethyl-5-hexenoate → 2(3H)-Furanone, 5-(2,2-dichloroethenyl)dihydro-4,4-dimethyl-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ethyl 4,6,6-trichloro-3,3-dimethyl-5-hexenoate | HCID 3042523 | — |
| 反応物 | 5-Hexenoic acid, 4,6,6-trichloro-3,3-dimethyl-, methyl ester | HCID 10999791 | — |
| 生成物 | 2(3H)-Furanone, 5-(2,2-dichloroethenyl)dihydro-4,4-dimethyl- | HCID 10198203 | 95% |
反応手順
The above procedure was repeated except that 27.4 parts of ethyl 3,3-dimethyl-4,6,6-trichloro-5-hexenoate was used in lieu of methyl 3,3-dimethyl-4,6,6-trichloro-5-hexenoate. In this case, 19.8 parts of 3,3-dimethyl-4-(2',2'-dichlorovinyl)-4-butanolide was obtained (yield 95%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04468521 |
| 出典データセット | uspto-grants-1984_08 |
| ORD ID | ord-af22ec5b42ba4adeb1f9266970015679 |
| 出典メモ | uspto-grants-1984_08 |