HuagongsheHuagongshe Chemistry Print Report · For research reference only
Picryl Chloride → 2,4,6-Trinitrophenylacetic acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Picryl Chloride | HCID 6953 | — |
| Reactant | Propanedioic acid, monoethyl ester | HCID 3595298 | — |
| Reactant | Sodium | HCID 5360545 | — |
| Product | 2,4,6-Trinitrophenylacetic acid | HCID 329464 | — |
Reaction Steps
2,4,6-Trinitrophenylacetic acid (mp 159°-160° C.) is prepared from 1-chloro-2,4,6-trinitrobenzene and ethyl malonate in the presence of metallio sodium in accordance with a procedure by M. Kimura in J. Pharm. Soc. Jpn., 73, 1216 (1953).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04997977 |
| Source dataset | uspto-grants-1991_03 |
| ORD ID | ord-1bfa364d9d334dda99662b3f56fb0083 |
| Source note | uspto-grants-1991_03 |