関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 4-Chlorophenol | HCID 4684 | — |
| 反応物 | Potassium Carbonate | HCID 11430 | — |
| 反応物 | 1-Bromo-4-nitrobenzene | HCID 11466 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | 1-Chloro-4-(4-nitrophenoxy)benzene | HCID 15786 | 95% |
反応手順
p-Chlorophenol (7 g), p-nitrobromobenzene (11.0 g) and potassium carbonate (9.02 g) in dimethylsufoxide (35 ml) were heated with stirring at 120° C. for 24 hours and cooled, and the mixture was poured into water. The resulting precipitate was collected by filtration and washed with water. The resultant was heated in a mixed solvent of methanol/water [4:1,(v/v)], and allowed to cool. The resulting product was collected by filtration to give 4-(4-chlorophenoxy)nitrobenzene (12.92 g).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04999378 |
|---|
| 出典データセット | uspto-grants-1991_03 |
|---|
| ORD ID | ord-abd26f5b9827450e90a5f585c85651fe |
|---|
| 出典メモ | uspto-grants-1991_03 |
|---|
