HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethanol → Ethyl 3,3-dimethylpent-4-enoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | Phenol | HCID 996 | — |
| Reactant | 1-(1,1-Diethoxyethoxy)-3-methylbut-2-ene | HCID 13321415 | — |
| Product | Ethyl 3,3-dimethylpent-4-enoate | HCID 82262 | 72% |
Reaction Steps
A mixture of 2.02 g of 1,1-diethoxy-1-(3-methyl-2-buten-1-yloxy)ethane and 20 mg of phenol was heated for 12 hours at 150°-160°, during which time ethanol was evolved. Distillation of the residue gave 1.12 g (72% yield) of ethyl 3,3-dimethyl-4-pentenoate, b.p. 80°-83°/57 mm.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04999451 |
| Source dataset | uspto-grants-1991_03 |
| ORD ID | ord-6660faa2fb4841c8a261dc641d29db7d |
| Source note | uspto-grants-1991_03 |