HuagongsheHuagongshe Chemistry Print Report · For research reference only
(+-)(2R*,3S*)-2-Methyl-2-nitro-1,3-butanediol → (+-)(2R*,3S*)-2-amino-2-methyl-1,3-butanediol acetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (+-)(2R*,3S*)-2-Methyl-2-nitro-1,3-butanediol | HCID 13375424 | — |
| Reactant | (+-)(2R*,3R*)-2-amino-2-methyl-1,3-butanediol acetate | HCID 86741969 | — |
| Product | (+-)(2R*,3S*)-2-amino-2-methyl-1,3-butanediol acetate | HCID 86741966 | 93.5% |
Reaction Steps
Using the procedure described for 32E, (±)-(2R*,3S*)-2-methyl-2-nitro-1,3-butanediol (32A, 41.1 g, 0.276 mol) gave 46.12 g (93.5%) of (±)-(2R*,3S*)-2-amino-2-methyl-1,3-butanediol acetate, mp 163°-165°, (C,H,N).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04999369 |
| Source dataset | uspto-grants-1991_03 |
| ORD ID | ord-77d962d9f6ee41eb875805ad52d9b273 |
| Source note | uspto-grants-1991_03 |