HRID359306

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID7701

4-Dodecylaniline

C18H31N

结构：O=S(=O)([O-])C(F)(F)F.c1ccc(-c2cc(-c3ccccc3)[o+]c(-c3ccccc3)c2)cc1

HCID2778031

AG-G-77560

C24H17F3O4S

PRODUCTS

生成物

结构：CCCCCCCCCCCCc1ccc(-[n+]2c(C)cc(C)cc2C)cc1.O=S(=O)([O-])C(F)(F)F

HCID20064821

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID702

Ethanol

C2H6O

PROCEDURE

实验过程

A 2.3-g portion (0.005 mole) of 2,4,6-triphenylpyrylium triflate is placed in a 500-ml round-bottom flask. To this, 200 ml of ethanol is added and then 1.3 g (0.005 mole) of p-dodecylaniline is added. The mixture is refluxed for about 20 hours. The ethanol is removed by evaporation to give a yellow waxy substance. This material is washed with ether which causes some yellow crystals to precipitate.

WORKUP

后处理

temperatureThe mixture is refluxed for about 20 hours
customThe ethanol is removed by evaporation
customto give a yellow waxy substance
washThis material is washed with ether which
customto precipitate

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-7f3fcc1c6d9047fca8c49414a0df1a8c
来源数据集: uspto-grants-1991_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05000873
来源说明: uspto-grants-1991_03

反应 SMILES

[O-:1][S:2]([C:5]([F:8])([F:7])[F:6])(=[O:4])=[O:3].[C:9]1([C:15]2[CH:20]=[C:19](C3C=CC=CC=3)C=C(C3C=CC=CC=3)[O+]=2)[CH:14]=C[CH:12]=[CH:11][CH:10]=1.[CH2:33]([C:45]1[CH:51]=[CH:50][C:48]([NH2:49])=[CH:47][CH:46]=1)[CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH3:44]>C(O)C>[O-:4][S:2]([C:5]([F:8])([F:7])[F:6])(=[O:3])=[O:1].[CH2:33]([C:45]1[CH:46]=[CH:47][C:48]([N+:49]2[C:20]([CH3:19])=[CH:15][C:9]([CH3:14])=[CH:10][C:11]=2[CH3:12])=[CH:50][CH:51]=1)[CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH3:44]