Aniline → HCID 86744679, compound

HRID 359658Notes

Reaction equation

HRID 359658 reaction equation
[S:1]([C:5]1[CH:11]=[CH:10][C:8]([CH3:9])=[CH:7][CH:6]=1)([O-:4])(=[O:3])=[O:2].[NH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1>>[NH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1.[S:1]([C:5]1[CH:11]=[CH:10][C:8]([CH3:9])=[CH:7][CH:6]=1)([O-:4])(=[O:3])=[O:2]

Participants

3

Reactant 2

HCID 6115Aniline3×HCID 85570p-Toluenesulfonate3×

Product 1

HCID 86744679HCID 86744679, compound

Procedure

Usable polymer films of polyaniline/tosylate are formed when the concentration range is limited to between about 0.8 and 1 M for tosylate and between about 0.05 and 0.2 M for aniline. The results of the half-cell battery test are summarized above in Table 4. No substantial difference in terms of the half-cell performance was observed when the concentration of aniline is increased from between about 0.1 M and 0.2 M or the concentration of tosylate is decreased from between about M to 0.8 M. However, a low concentration of aniline, i.e. 0.05 M, gives a poorer performance (PAN 96). A preferred concentration range is: aniline: 0.1 M to 0.2 M; tosylate: 0.8 M to 1 M.

Workup

  1. customThe results of the half-cell battery test
  2. temperatureis increased from between about 0.1 M and 0.2 M
  3. concentrationHowever, a low concentration of aniline, i.e. 0.05 M
  4. customgives a poorer performance (PAN 96)

Sources & evidence

ORD record
ord-acda09da293a44daac5d97efa42b200a
Source dataset
uspto-grants-1991_03
Patent number
US05002700

Reaction notes

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