1,2-Diallyloxybenzene → 1,2-Diallyloxybenzene

HRID 360485Notes

Reaction equation

HRID 360485 reaction equation
C=CCOc1ccccc1OCC=C>CC#N.CC#N.O>C=CCc1ccc(CC=C)c(O)c1O.C=CCc1ccc(O)c(O)c1CC=C

Participants

7

Reactant 1

HCID 778941,2-Diallyloxybenzene

Product 3

HCID 778941,2-DiallyloxybenzeneYield 84.293%HCID 131583253,4-Diallylbenzene-1,2-diolYield 3.431%HCID 132276783,6-Bis(prop-2-enyl)benzene-1,2-diolYield 6.541%

Reagents, catalysts & solvents 3

HCID 6342AcetonitrileSolventHCID 18373917Acetonitrile--water (1/1)SolventHCID 7500EthylbenzeneInternal standard

Conditions

Temperature
225 °C
Other
Reaction carried out in transient flow with ramps to vary the binary solvent composition, temperature and residence time. This reaction represents a single HPLC measurement sampled from within a transient flow ramp. Conditions are an estimate of what the reaction sample was exposed to prior to analysis.

Workup

  1. temperatureThe solution flowed through a customized cooling system made from an aluminum block and a Peltier assembly to quench the reaction.
  2. aliquotA Vici 4 port 2 position sampling valve sampled small aliquots (500 nL) into the HPLC for online analysis measurements of the reaction.

Sources & evidence

ORD record
ord-9424f3f4d71647babf05da3fbe9d1cbc
Source dataset
Transient flow exploration of the effect of temperature, residence time and binary solvent ratios on a uni-molecular allyl substituted catechol reaction.
Original link
View source

Reaction notes

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