HuagongsheHuagongshe Chemistry Print Report · For research reference only
Alumina → Methyl cyclohexanecarboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Alumina | HCID 9989226 | — |
| Reactant | Dimethyl Cyclohexane-1,1-dicarboxylate | HCID 10965525 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | Methyl cyclohexanecarboxylate | HCID 20748 | 316% |
Reaction Steps
Per hour a solution of 4.5 g of dimethyl 1,1-cyclohexanedicarboxylate in 4.5 g of methanol was passed at 275° C. over 5 g of aluminum oxide. The exit mixture obtained over 6 hours (36.5 g) was distilled to yield 10.1 g of methyl cyclohexanecarboxylate (53%, based on diester used) and 7.7 g of the starting material.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05412120 |
| Source dataset | uspto-grants-1995_05 |
| ORD ID | ord-2cbfd30ef447489789c90ee246ab483c |
| Source note | uspto-grants-1995_05 |