1,2-Diallyloxybenzene → 1,2-Diallyloxybenzene

HRID 360926노트

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HRID 360926 반응식
C=CCOc1ccccc1OCC=C>CC(=O)N(C)C.CCCCCCCCCCO>C=CCc1ccc(CC=C)c(O)c1O.C=CCc1ccc(O)c(O)c1CC=C

참가 물질

7

반응물 1

HCID 778941,2-Diallyloxybenzene

생성물 3

HCID 778941,2-Diallyloxybenzene수율 90.802%HCID 131583253,4-Diallylbenzene-1,2-diol수율 0%HCID 132276783,6-Bis(prop-2-enyl)benzene-1,2-diol수율 0%

시약·촉매·용매 3

HCID 81741-Decanol용매HCID 31374Dimethylacetamide용매HCID 7500Ethylbenzene내부 표준

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온도
175 °C
기타
Reaction carried out in transient flow with ramps to vary the binary solvent composition, temperature and residence time. This reaction represents a single HPLC measurement sampled from within a transient flow ramp. Conditions are an estimate of what the reaction sample was exposed to prior to analysis.

후처리

  1. temperatureThe solution flowed through a customized cooling system made from an aluminum block and a Peltier assembly to quench the reaction.
  2. aliquotA Vici 4 port 2 position sampling valve sampled small aliquots (500 nL) into the HPLC for online analysis measurements of the reaction.

출처 및 근거

ORD 기록
ord-746424d2ef8a4045a17df431ea987159
출처 데이터셋
Transient flow exploration of the effect of temperature, residence time and binary solvent ratios on a uni-molecular allyl substituted catechol reaction.
원본 링크
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