Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sodium Carbonate → 5-Phenyl-2-picoline N-oxide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sodium Carbonate | HCID 10340 | — |
| 반응물 | m-Chloroperbenzoic acid | HCID 70297 | — |
| 반응물 | 2-Methyl-5-phenylpyridine | HCID 76744 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | 5-Phenyl-2-picoline N-oxide | HCID 14980528 | — |
반응 단계
A solution of 3-phenyl-6-methyl pyridine (2.36 g, 13.95 mmol), in CH2Cl2 (40 mL) at 0° C. was treated with MCPBA (3.58 g, 13.95 mmol) for 1 hour. Saturated aq. Na2CO3 (50 mL) was added and the reaction was extracted with CH2Cl2 (20 mL). The organic extracts were dried (MgSO4), and the solvent evaporated in vacuo to afford the title compound.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05872136 |
| 출처 데이터셋 | uspto-grants-1999_02 |
| ORD ID | ord-05a8840426d74b2e8630c01407e52f00 |
| 출처 메모 | uspto-grants-1999_02 |