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HRID363728

反应详情

EQUATION

反应方程式

HRID 363728 的结构方程式

REACTANTS

反应物

2
结构：C[Si](C)(C)Cl
HCID6397

Chlorotrimethylsilane

C3H9ClSi

结构：CC(C)C(=O)C(C)C
HCID11271

2,4-Dimethylpentan-3-one

C7H14O

PRODUCTS

生成物

1
结构：CC(C)=C(O[Si](C)(C)C)C(C)C
HCID11095327

Silane, trimethyl[[2-methyl-1-(1-methylethyl)-1-propenyl]oxy]-

C10H22OSi

PROCEDURE

实验过程

Reaction between 2,4-dimethyl-3-pentanone (1.2.4.3), trimethylsilyl chloride, and base gave 2,4-dimethyl-3-trimethysilyloxy-2-pentene (1.2.4.4) which was reacted with 1-fluoropyridinium triflate (1.2.4.5) to form 2,4-dimethyl-2-fluoro-3-pentanone (1.2.4.6). This product was reacted with (CH3)3S(O)+I- to form the title compound (1.2.4.2). ##STR31##