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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 363994Generated: October 26, 2026

Nitric Acid → 4-Nitrotoluene

https://huagongshe.com/reaction/363994

Reaction equation

Participants

RoleNameHCIDCharge
ReactantNitric AcidHCID 944—
Reactant2,3-DinitrotolueneHCID 11761—
SolventTolueneHCID 1140—
Product4-NitrotolueneHCID 7473—

Reaction Steps

Commercially, nitroaromatics, and particularly dinitrotoluene, are produced by the mixed acid nitration of toluene, the mixed acid being a mixture of concentrated sulfuric and concentrated nitric acid. In the production of dinitrotoluene process, for example, toluene is first nitrated to form mononitrotoluene and then separated from the spent acid aqueous phase. The crude mononitrotoluene is then dinitrated with fresh acid in a second nitration stage. As is known the dinitrotoluene product recovered from the dinitration reactor contains impurities, primarily nitrophenolics, such as nitrocresol and picric acid.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS04604214
Source datasetuspto-grants-1986_08
ORD IDord-941078a6f7ec4480a40d69fbb9055b3f
Source noteuspto-grants-1986_08