Sulfuryl chloride → HCID 54423660, compound

HRID 364603Notes

Reaction equation

HRID 364603 reaction equation
[CH2:1]([O:9][N:10]=[C:11]([C:17](=[O:19])[CH3:18])[C:12]([O:14][CH2:15][CH3:16])=[O:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].S(Cl)([Cl:23])(=O)=O>C(O)(=O)C>[CH2:1]([O:9][N:10]=[C:11]([C:17](=[O:19])[CH2:18][Cl:23])[C:12]([O:14][CH2:15][CH3:16])=[O:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

Participants

4

Reactant 2

HCID 24648Sulfuryl chlorideHCID 54485478HCID 54485478, compound

Product 1

HCID 54423660HCID 54423660, compoundYield 90.9%

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

Ethyl 2-n-octyloxyimino-3-oxobutyrate (syn isomer, 165.5 g.), sulfuryl chloride (84.7 g.) and acetic acid (165 ml.) were treated in a similar manner to that of Example F-(2) to give ethyl 2-n-octyloxyimino-4-chloro-3-oxobutyrate (syn isomer, 169.6 g.), oil.

Sources & evidence

ORD record
ord-460cc0cf48d04cacb05ca81ab92206fb
Source dataset
uspto-grants-1986_08
Patent number
US04604456

Reaction notes

Loading…