Silver → HCID 86740194, compound

HRID 364687Notes

Reaction equation

HRID 364687 reaction equation
[CH2:1]([S:10]([O-:12])=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].[Na+].[Ag:14].[N+]([O-])([O-])=O.[Ag+]>O>[CH2:1]([S:10]([O-:12])=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].[Ag+:14]

Participants

5

Reactant 3

HCID 23954SilverHCID 24470Silver NitrateHCID 86740195HCID 86740195, compound2×

Product 1

HCID 86740194HCID 86740194, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

Using the material from Example 3, 3 g of sodium nonylsulfinate was dissolved in 150 ml H2O at room temperature. Four 25 ml portions of a silver solution prepared by adding 3.5 ml 3N AgNO3 to 100 ml H2O were added with stirring to the dissolved sodium nonylsulfinate to give a final pH of 6.6 and a pAg of 6.6 (240 mV). The product was filtered, washed first with water and then with water/methanol, and then dried. Infrared spectra of the silver nonylsulfinate showed strong absorption at 1080, 1060 and 970. The salt did not appear to be appreciably light sensitive when exposed to room light for a period of several days.

Workup

  1. additionwere added
  2. customto give a final pH of 6.6
  3. filtrationThe product was filtered
  4. washwashed first with water
  5. dry with materialwith water/methanol, and then dried
  6. customspectra of the silver nonylsulfinate showed strong absorption at 1080, 1060 and 970
  7. waitexposed to room light for a period of several days

Sources & evidence

ORD record
ord-f52ba9a901c74b11b240548935721ded
Source dataset
uspto-grants-1986_08
Patent number
US04605753

Reaction notes

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