HCID 11000069, compound → HCID 57003832, compound

HRID 36479Notes

Reaction equation

HRID 36479 reaction equation
[CH:1]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6](C(C)C)[C:5]=1[O:13][CH2:14][C:15]1C=CC=[CH:17][CH:16]=1)([CH3:3])[CH3:2]>C(O)C.C(O)(=O)C.[Pd]>[CH:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[O:13][CH2:14][CH:15]=[CH:16][CH3:17])([CH3:3])[CH3:2]

Participants

5

Reactant 1

HCID 11000069HCID 11000069, compound

Product 1

HCID 57003832HCID 57003832, compound

Reagents, catalysts & solvents 3

HCID 176Acetic AcidSolventHCID 702EthanolSolventHCID 23938PalladiumSolvent

Procedure

Benzyl (2,6-diisopropylphenyl) ether 60 mg was dissolved in 20 ml of anhydrous ethanol solution of 5% acetic acid. After adding 30 mg of active carbon in 10% palladium thereinto, it was dissolved under hydrogen gas for 15 hours. Thus-obtained mixture Was washed with water and saturated sodium chloride aqueous solution. The resultant was dried with anhydrous magnesium sulfate and then concentrated.

Workup

  1. dissolutionit was dissolved under hydrogen gas for 15 hours
  2. customThus-obtained mixture
  3. washWas washed with water and saturated sodium chloride aqueous solution
  4. dry with materialThe resultant was dried with anhydrous magnesium sulfate
  5. concentrationconcentrated

Sources & evidence

ORD record
ord-9f5dfadd86774bf5b813c7dba6b86638
Source dataset
uspto-grants-1995_05
Patent number
US05414156

Reaction notes

Loading…