HRID366281

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CCC(CCC(C)C1CCC2C3CCC4CC(O)CCC4(C)C3CCC12C)C(C)C

HCID6743

未命名化合物

结构：CC[C@H](CC[C@@H](C)[C@H]1CC[C@H]2[C@@H]3CC[C@H]4C[C@@H](O)CC[C@]4(C)[C@H]3CC[C@]12C)C(C)C

HCID241572

(3beta,5alpha)-Stigmastan-3-ol

C29H52O

PRODUCTS

生成物

结构：CC[C@H](CC[C@@H](C)[C@H]1CC[C@H]2[C@@H]3CC=C4C[C@@H](O)CC[C@]4(C)[C@H]3CC[C@]12C)C(C)C

HCID222284

(-)-beta-Sitosterol

C29H50O

PROCEDURE

实验过程

Pure sitostanol or stigmastanol is a commercial product obtained by catalytic hydrogenation of sitosterol. Its synthesis from beta-sitosterol was described in 1937: Bernstein, Wallis, J. Org. Chem Soc., 2, 341.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-7def4175f2804e9789ddea2347181204
来源数据集: uspto-grants-2000_10
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06129924
来源说明: uspto-grants-2000_10

反应 SMILES

[CH3:1][CH2:2][CH:3]([CH:28]([CH3:30])[CH3:29])[CH2:4][CH2:5][CH:6]([CH:8]1[C:12]2([CH3:27])[CH2:13][CH2:14][CH:15]3[C:20]4([CH3:26])[CH2:21][CH2:22][CH:23]([OH:25])[CH2:24][CH:19]4[CH2:18][CH2:17][CH:16]3[CH:11]2[CH2:10][CH2:9]1)[CH3:7].CC[C@@H](C(C)C)CC[C@H]([C@@H]1[C@@]2(C)CC[C@@H]3[C@@]4(C)CC[C@H](O)C[C@@H]4CC[C@H]3[C@@H]2CC1)C>>[CH3:1][CH2:2][C@@H:3]([CH:28]([CH3:29])[CH3:30])[CH2:4][CH2:5][C@H:6]([C@@H:8]1[C@@:12]2([CH3:27])[CH2:13][CH2:14][C@@H:15]3[C@@:20]4([CH3:26])[CH2:21][CH2:22][C@H:23]([OH:25])[CH2:24][C:19]4=[CH:18][CH2:17][C@H:16]3[C@@H:11]2[CH2:10][CH2:9]1)[CH3:7]