Thionyl Chloride → HCID 131719003, compound

HRID 36823Notes

Reaction equation

HRID 36823 reaction equation
[CH2:1]([O:9][C:10]1[CH:15]=[CH:14][C:13]([C:16]2[C:17]([C:22]3[CH:27]=[CH:26][C:25]([C:28]([OH:30])=O)=[CH:24][CH:23]=3)=[CH:18][CH:19]=[CH:20][CH:21]=2)=[CH:12][CH:11]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].S(Cl)([Cl:33])=O>>[CH2:1]([O:9][C:10]1[CH:15]=[CH:14][C:13]([C:16]2[C:17]([C:22]3[CH:27]=[CH:26][C:25]([C:28]([Cl:33])=[O:30])=[CH:24][CH:23]=3)=[CH:18][CH:19]=[CH:20][CH:21]=2)=[CH:12][CH:11]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

Participants

3

Reactant 2

HCID 24386Thionyl ChlorideHCID 131719004HCID 131719004, compound

Product 1

HCID 131719003HCID 131719003, compound

Procedure

After 1.6 g of 4-n-octyloxyterphenyl-4"-carboxylic acid was heated with an excess amount of thionyl chloride under reflux condition for 6 hours, unreacted thionyl chloride was distilled off to obtain 4-n-octyloxyterphenyl-4"-carboxylic acid chloride.

Workup

  1. temperatureunder reflux condition for 6 hours
  2. distillationunreacted thionyl chloride was distilled off

Sources & evidence

ORD record
ord-d742110c3af64f9e96ac9226d50d2182
Source dataset
uspto-grants-1995_05
Patent number
US05417885

Reaction notes

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