Hexachloroethane → HCID 18630146, compound

HRID 368578Notes

Reaction equation

HRID 368578 reaction equation
[CH2:1]([N:3]([CH2:17][CH3:18])[C:4](=[O:16])[C:5]1[CH:10]=[CH:9][C:8]([CH3:11])=[CH:7][C:6]=1[Si:12]([CH3:15])([CH3:14])[CH3:13])[CH3:2].[Cl:19]C(Cl)(Cl)C(Cl)(Cl)Cl>>[CH2:17]([N:3]([CH2:1][CH3:2])[C:4](=[O:16])[C:5]1[C:6]([Si:12]([CH3:15])([CH3:14])[CH3:13])=[CH:7][C:8]([CH3:11])=[CH:9][C:10]=1[Cl:19])[CH3:18]

Participants

3

Reactant 2

HCID 6214HexachloroethaneHCID 18630203HCID 18630203, compound

Product 1

HCID 18630146HCID 18630146, compound

Procedure

The title compound was prepared from the compound of Example 58 and 1.2 eq hexachloroethane according to General Method A. Purification by HPLC with 1:9 ethyl acetate/hexanes afforded 1.6 g of the title compound as a clear oil, a 54% yield.

Workup

  1. customPurification by HPLC with 1:9 ethyl acetate/hexanes

Sources & evidence

ORD record
ord-50ff91346b3b4786b6414561b8fb350b
Source dataset
uspto-grants-2000_10
Patent number
US06133252

Reaction notes

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