(N,N-dimethylaminoethyl)cyclopentadiene → HCID 178483396, compound

HRID 370127Notes

Reaction equation

HRID 370127 reaction equation
[CH3:1][N:2]([CH2:4][CH2:5][CH2:6][CH:7]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH:9]=[CH:8]1)[CH3:3].CN(CCC1CC=CC=1)C.[Cl-:26].[Cl-].[Cl-].[CH:29]1([Zr+3:34])[CH:33]=[CH:32][CH:31]=[CH:30]1.[Cl-].[Cl-].[Cl-].C[Zr](C)(C)(C)(C)C1C=CC=C1>>[Cl-:26].[Cl-:26].[CH3:1][N:2]([CH2:4][CH2:5][CH2:6][CH:7]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH:9]=[C:8]1[Zr+2:34][CH:29]1[CH:33]=[CH:32][CH:31]=[CH:30]1)[CH3:3]

Participants

5

Reactant 4

HCID 12154709(N,N-dimethylaminoethyl)cyclopentadieneHCID 230024761(N,N-dimethylaminopropyl)indeneHCID 178477801HCID 178477801, compoundHCID 178478629HCID 178478629, compound

Product 1

HCID 178483396HCID 178483396, compoundYield 40%

Procedure

Example 1 was repeated in the same manner as described except that 1-(N,N-dimethylaminopropyl)indene was substituted for (N,N-dimethylaminoethyl)cyclopentadiene and that cyclopentadienylzirconium trichloride was substituted for pentamethylcyclopentadienylzirconium trichloride. The yield was 40.0%. The physical properties of the product are as follows:

Sources & evidence

ORD record
ord-826e7b416056492497375953274c78d9
Source dataset
uspto-grants-2000_10
Patent number
US06140448

Reaction notes

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