HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl Isocyanate → N-methyl-N[2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenyl](N-methyl)carbamoyloxyamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl Isocyanate | HCID 12228 | — |
| Reactant | HCID 20275650 | HCID 20275650 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | N-methyl-N[2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenyl](N-methyl)carbamoyloxyamine | HCID 54362184 | — |
Reaction Steps
To a solution of N-methyl-N-[2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenyl]hydroxyamine (700 mg, 1.93 mmol) in anhydrous THF (10 ml) is added methylisocyanate (220 mg, 2 eq.). The mixture is stirred at RT for 4 hours. The solvent and excess methlisocyanate are removed to yield N-methyl-N[2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenyl](N-methyl)carbamoyloxyamine.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04526608 |
| Source dataset | uspto-grants-1985_07 |
| ORD ID | ord-22ff44d5be734c308ec81d3bb1add429 |
| Source note | uspto-grants-1985_07 |