HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dichloromethane → 3-Octanoyloxy-2-(4'-methylphenyl)-5,5-dimethyl-2-cyclohexenone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dichloromethane | HCID 6344 | — |
| Reactant | Octanoyl chloride | HCID 8124 | — |
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | 2-(4'-Methylphenyl)-5,5-dimethyl-1,3-cyclohexanedione | HCID 13259770 | — |
| Product | 3-Octanoyloxy-2-(4'-methylphenyl)-5,5-dimethyl-2-cyclohexenone | HCID 20275821 | 71% |
Reaction Steps
Using the procedure described in Example III and starting with 3.00 g (0.0130 mol) of 2-(4'-methylphenyl)-5,5-dimethyl-1,3-cyclohexanedione, 1.59 g (0.0098 mol) of octanoyl chloride, 2.63 g (0.0260 mol) of triethylamine, and 30 mol of methylene chloride, 2.5 g (71% yield) of a clear, colorless oil was obtained as the desired product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04526723 |
| Source dataset | uspto-grants-1985_07 |
| ORD ID | ord-55dd89a8e8574dfead7a3b3ed5ff2bb6 |
| Source note | uspto-grants-1985_07 |