Benzyl azide → HCID 13518833, compound

HRID 370529Notes

Reaction equation

HRID 370529 reaction equation
[CH2:1]([N:8]=[N+:9]=[N-:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH2:11]([S:18]([C:21]#[N:22])(=[O:20])=[O:19])[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1>>[CH2:1]([N:8]1[C:21]([S:18]([CH2:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)(=[O:20])=[O:19])=[N:22][N:10]=[N:9]1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 12152Benzyl azideHCID 13849791HCID 13849791, compound

Product 1

HCID 13518833HCID 13518833, compound

Procedure

Heating a mixture of benzyl azide (Fr. Moulin, loc. cit.) and benzylsulfonyl cyanide as in Example 2 gives the title compound, m.p. 94°-96° C.

Workup

  1. temperatureHeating

Sources & evidence

ORD record
ord-89f4175a3fb5463790a6f05aecbdd5c0
Source dataset
uspto-grants-1985_07
Patent number
US04526978

Reaction notes

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