Aluminum(III) Chloride → HCID 20274115, compound

HRID 371046Notes

Reaction equation

HRID 371046 reaction equation
[C:1]([C:5]1[CH:21]=[CH:20][C:8]([O:9][C:10]2[CH:15]=[C:14]([O:16]C)[CH:13]=[CH:12][C:11]=2[O:18]C)=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2].[Cl-].[Cl-].[Cl-].[Al+3]>C1C=CC=CC=1>[C:1]([C:5]1[CH:21]=[CH:20][C:8]([O:9][C:10]2[CH:15]=[C:14]([OH:16])[CH:13]=[CH:12][C:11]=2[OH:18])=[CH:7][CH:6]=1)([CH3:4])([CH3:2])[CH3:3]

Participants

4

Reactant 2

HCID 6451240Aluminum(III) ChlorideHCID 20274110HCID 20274110, compound

Product 1

HCID 20274115HCID 20274115, compoundYield 79.2%

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Conditions

Temperature
100 °C

Procedure

A separable flask was charged with 140 g of the thus-obtained 2-(4-t-butylphenoxy)-1,4-dimethoxybenzene, 1000 g of aluminum trichloride and 500 cc of benzene. The mixture was stirred at 100° C. for 2 hours and was thrown into ice-hydrochloric acid. The formed precipitate was recovered by filtration, washed with water and dried to obtain about 100 g of 2-(4-t-butylphenoxy)hydroquinone.

Workup

  1. filtrationThe formed precipitate was recovered by filtration
  2. washwashed with water
  3. customdried

Sources & evidence

ORD record
ord-0afdef74ff7b4bf98fa619dbce794d75
Source dataset
uspto-grants-1985_07
Patent number
US04529565

Reaction notes

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