Silver → HCID 86740194, compound

HRID 371074Notes

Reaction equation

HRID 371074 reaction equation
[CH2:1]([S:10]([O-:12])=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].[Na+].[Ag:14].[N+]([O-])([O-])=O.[Ag+]>O>[CH2:1]([S:10]([O-:12])=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].[Ag+:14]

Participants

5

Reactant 3

HCID 23954SilverHCID 24470Silver NitrateHCID 86740195HCID 86740195, compound2×

Product 1

HCID 86740194HCID 86740194, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

Using the material from Example 3, 3 g of sodium nonylsulfinate was dissolved in 150 ml H2O at room temperature. Four 25 ml portions of a silver solution prepared by adding 3.5 ml 3N AgNO3 to 100 ml H2O were added with stirring to the dissolved sodium nonylsulfinate to give a final pH of 6.6 and a pAg of 6.6 (240 mV). The product was filtered, washed first with water and then with water/methanol, and then dried. Infrared spectra of the silver nonylsulfinate showed strong absorption at 1080, 1060 and 970. The salt did not appear to be appreciably light sensitive when exposed to room light for a period of several days.

Workup

  1. additionwere added
  2. customto give a final pH of 6.6
  3. filtrationThe product was filtered
  4. washwashed first with water
  5. dry with materialwith water/methanol, and then dried
  6. customspectra of the silver nonylsulfinate showed strong absorption at 1080, 1060 and 970
  7. waitexposed to room light for a period of several days

Sources & evidence

ORD record
ord-ae7cd5f24a2e49fe9522c40e1bcfdf3e
Source dataset
uspto-grants-1985_07
Patent number
US04529689

Reaction notes

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