Methyl iodide → HCID 20274395, compound

HRID 371134Notes

Reaction equation

HRID 371134 reaction equation
[N:1]([C:4]1[CH:9]=[CH:8][C:7]([C:10]23[CH:18]4[CH2:19][CH:15]([CH2:16][CH2:17]4)[CH:14]2[CH2:13][N:12]([CH3:20])[CH2:11]3)=[CH:6][CH:5]=1)=[N+:2]=[N-:3].[CH3:21][I:22]>CCOCC>[I-:22].[N:1]([C:4]1[CH:5]=[CH:6][C:7]([C:10]23[CH:18]4[CH2:19][CH:15]([CH2:16][CH2:17]4)[CH:14]2[CH2:13][N+:12]([CH3:21])([CH3:20])[CH2:11]3)=[CH:8][CH:9]=1)=[N+:2]=[N-:3]

Participants

4

Reactant 2

HCID 6328Methyl iodideHCID 20274398HCID 20274398, compound

Product 1

HCID 20274395HCID 20274395, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

A mixture of 150 mg of 3a-(4-azidophenyl)octahydro-2-methyl-4,7-methano-1H-isoindole and 0.05 ml of methyl iodide in 4 ml of ether was allowed to stand for 2 weeks to give 200 mg of the desired product as a yellow solid.

Workup

  1. waitto stand for 2 weeks

Sources & evidence

ORD record
ord-923bef8c4d404d68af7ded5a85027a62
Source dataset
uspto-grants-1985_07
Patent number
US04529736

Reaction notes

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