HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 371169Generated: October 26, 2026
Phosgene → Carbonic acid;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol
https://huagongshe.com/reaction/371169
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Phosgene | HCID 6371 | — |
| Reactant | Bisphenol A | HCID 6623 | — |
| Reactant | 4-tert-Butylphenol | HCID 7393 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | Carbonic acid;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol | HCID 159987 | — |
Reaction Steps
Into a mixture of 272.4 parts by weight of 4,4'-dihydroxy diphenyl-2,2-propane (bisphenol A), 145 parts by weight of sodium hydroxide, 1045 parts by weight of deionized water, 1330 parts by weight (1.0 liter) of methylene chloride and 5.55 parts by weight p-tertbutylphenol, 150 parts by weight of carbonyl chloride were added over a period of 0.5 hour with stirring and at a temperature of 25° C. This resulted in solution of bisphenol A polycarbonate oligomers in methylene chloride at a concentration of about 23 percent by weight in the organic phase
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US04529791 |
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| Source dataset | uspto-grants-1985_07 |
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| ORD ID | ord-7c6ea5b2c04f4405a9cf396597df751b |
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| Source note | uspto-grants-1985_07 |
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