Nickel Dichloride → HCID 86740208, compound

HRID 371372Notes

Reaction equation

HRID 371372 reaction equation
[CH2:1]([O:8][S:9]([O-:12])(=[O:11])=[S:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Na+].Cl[Ni:15]Cl>CO>[CH2:1]([O:8][S:9]([O-:12])(=[O:11])=[S:10])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1.[Ni+2:15].[CH2:1]([O:8][S:9]([O-:12])(=[O:11])=[S:10])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

4

Reactant 2

HCID 24385Nickel DichlorideHCID 23692423HCID 23692423, compound

Product 1

HCID 86740208HCID 86740208, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Sodium benzylthiosulphate (57.5 g) and anhydrous NiCl2 (14.2 g) were mixed in absolute methanol (150 ml) at room temperature, and the mixture was stirred for 24 hours. It was then filtered, and methanol was evaporated from the filtrate. The residue was treated with water (50 ml) to displace the residual methanol, and the resulting solution was evaporated to dryness under vacuum, at a temperature not exceeding 50° C.

Workup

  1. filtrationIt was then filtered
  2. custommethanol was evaporated from the filtrate
  3. additionThe residue was treated with water (50 ml)
  4. customthe resulting solution was evaporated to dryness under vacuum, at a temperature not
  5. customexceeding 50° C.

Sources & evidence

ORD record
ord-267de7fc99424dc2abb9e9bc65ccdd5d
Source dataset
uspto-grants-1985_07
Patent number
US04532080

Reaction notes

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