Triethylamine → HCID 20355088, compound

Participants

Reaction Steps

A mixture of 7.1 g. 3-allylthio-1,2,4-triazole, (m.p. 27° - 30° C., prepared from 3-mercapto-1,2,4-triazole in an analogous manner to that described in Example 1), 8.0 g. diallylcarbamoyl chloride, 7.5 ml. dry triethylamine and 100 ml. dry tetrahydrofuran was refluxed under anhydrous conditions for 48 hours. The reaction mixture was worked up as described in Example 1 to give 1-diallylcarbamoyl-3-allylthio-1,2,4-triazole, b.p. 120° - 122° C./0.1 mm. (95.2% 1-isomer by GLC assay).

Provenance & Evidence