Sodium Hydroxide → HCID 131711093, compound

HRID 371795Notes

Reaction equation

HRID 371795 reaction equation
COCC[O:5][C:6](=[O:82])[C:7]1[CH:19]=[C:18]([NH:20][S:21]([C:24]2[CH:25]=[C:26]3[C:31](=[CH:32][CH:33]=2)[C:30]([S:34]([NH:37][C:38]2[CH:39]=[C:40]([C:51]([O:53]CCOC)=[O:52])[CH:41]=[C:42]([CH:50]=2)[C:43]([O:45]CCOC)=[O:44])(=[O:36])=[O:35])=[CH:29][C:28]([S:58]([NH:61][C:62]2[CH:63]=[C:64]([C:75]([O:77]CCOC)=[O:76])[CH:65]=[C:66]([CH:74]=2)[C:67]([O:69]CCOC)=[O:68])(=[O:60])=[O:59])=[CH:27]3)(=[O:23])=[O:22])[CH:17]=[C:9]([C:10]([O:12]CCOC)=[O:11])[CH:8]=1.[OH-].[Na+:84]>>[Na+:84].[Na+:84].[Na+:84].[Na+:84].[Na+:84].[Na+:84].[C:30]1([S:34]([NH:37][C:38]2[CH:39]=[C:40]([C:51]([O-:53])=[O:52])[CH:41]=[C:42]([CH:50]=2)[C:43]([O-:45])=[O:44])(=[O:35])=[O:36])[C:31]2[C:26](=[CH:25][C:24]([S:21]([NH:20][C:18]3[CH:17]=[C:9]([C:10]([O-:12])=[O:11])[CH:8]=[C:7]([CH:19]=3)[C:6]([O-:82])=[O:5])(=[O:22])=[O:23])=[CH:33][CH:32]=2)[CH:27]=[C:28]([S:58]([NH:61][C:62]2[CH:63]=[C:64]([C:75]([O-:77])=[O:76])[CH:65]=[C:66]([CH:74]=2)[C:67]([O-:69])=[O:68])(=[O:59])=[O:60])[CH:29]=1

Participants

3

Reactant 2

HCID 14798Sodium HydroxideHCID 544288385,5',5"-[1,3,6-Naphthalenetriyltris(sulfonylimino)]triisophthalic acid hexakis(2-methoxyethyl)ester

Product 1

HCID 131711093HCID 131711093, compound

Procedure

A mixture of 9.05 g of the product of Example 3 and 45 ml of 2N sodium hydroxide is stirred at room temperature for 45 minutes. The solution is filtered, the filtrate is neutralized with 2.5 ml of glacial acetic acid, and diluted with 250 ml of ethanol. The product formed is collected by filtration, washed with ethanol followed by ether and dried to give 7.85 g of the product of the Example as a yellow powder.

Workup

  1. filtrationThe solution is filtered
  2. additiondiluted with 250 ml of ethanol
  3. customThe product formed
  4. filtrationis collected by filtration
  5. washwashed with ethanol
  6. customdried

Sources & evidence

ORD record
ord-f51d8e64c8184834965d023bace5d5b0
Source dataset
uspto-grants-1978_05
Patent number
US04087613

Reaction notes

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