Acetone → HCID 22763762, compound

HRID 371981Notes

Reaction equation

HRID 371981 reaction equation
[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH:9]([NH2:19])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[P:20](=[O:24])([OH:23])([OH:22])[OH:21].CC(C)=O>C(O)C>[P:20]([OH:24])([OH:23])([OH:22])=[O:21].[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH:9]([NH2:19])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

Participants

5

Reactant 3

HCID 180AcetoneHCID 1004Phosphoric Acid2×HCID 20329979HCID 20329979, compound

Product 1

HCID 22763762HCID 22763762, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

0.1 mole (26.8g) of octadecen-9-ylamine (oleylamine) is dissolved in 100 ml of ethanol and 0.1 mole of phosphoric acid (11.52g of 85% aqueous acid) is added dropwise while stirring. After all the phosphoric acid has been added the resulting solution is stirred for some time. 50 ml of acetone is then added and the resulting product filtered off with a suction filter, washed with a little petroleum ether and reprecipitated once from ethanol. The product sinters at 110° C.

Workup

  1. stirringis stirred for some time
  2. filtrationthe resulting product filtered off with a suction
  3. filtrationfilter
  4. washwashed with a little petroleum ether
  5. customreprecipitated once from ethanol
  6. customat 110° C.

Sources & evidence

ORD record
ord-287dfc42270349269bc8c579084a669f
Source dataset
uspto-grants-1978_05
Patent number
US04088752

Reaction notes

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