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HRID372007

反应详情

EQUATION

反应方程式

HRID 372007 的结构方程式

REACTANTS

反应物

3
结构：Cl.Cl.Nc1c(F)c(N)c(F)c(F)c1F
HCID149026

Tetrafluoro-m-phenylenediamine dihydrochloride

C6H6Cl2F4N2

结构：CSC(N)=[NH2+].CSC(N)=[NH2+].O=S(=O)([O-])[O-]
HCID6604939

S-Methylisothiourea hemisulfate

C4H14N4O4S3

结构：NCCCc1ncc[nH]1
HCID13290797

3-(1H-Imidazol-2-yl)propan-1-amine

C6H11N3

PRODUCTS

生成物

1
结构：N=C(N)NCCCc1ncc[nH]1.O.O=S(=O)(O)O
HCID178512791

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：O
溶剂HCID962

Water

H2O

PROCEDURE

实验过程

A solution of 2-(3-aminopropyl)imidazole, prepared from its dihydrochloride (0.9 g) by means of an ion-exchange resin (OH-), and S-methylthiouronium sulphate (1.26 g) in water (20 ml) is heated under reflux for 18 hours. The product, isolated in a manner similar to that described in Example 1, is recrystallized from aqueous ethanol yielding 3-(2-imidazolyl)propylguanidine sulphate monohydrate, m.p. 260°-262° C (dec.).

WORKUP

后处理

  1. temperatureis heated
  2. temperatureunder reflux for 18 hours
  3. customThe product, isolated in a manner similar to
  4. customis recrystallized from aqueous ethanol