4,4'-(2-Ethyl-2-nitrotrimethylene)dimorpholine → 4-(2-Nitrobutyl)morpholine - 4,4'-(2-ethyl-nitrotrimethylene)dimorpholine mixture

HRID 372082Notes

Reaction equation

HRID 372082 reaction equation
[N+:1]([CH:4]([CH2:12][CH3:13])[CH2:5][N:6]1[CH2:11][CH2:10][O:9][CH2:8][CH2:7]1)([O-:3])=[O:2].[N+:14]([C:17]([CH2:32][CH3:33])([CH2:25][N:26]1[CH2:31][CH2:30][O:29][CH2:28][CH2:27]1)[CH2:18][N:19]1[CH2:24][CH2:23][O:22][CH2:21][CH2:20]1)([O-:16])=[O:15]>>[CH3:13][CH2:12][CH:4]([N+:1]([O-:3])=[O:2])[CH2:5][N:6]1[CH2:11][CH2:10][O:9][CH2:8][CH2:7]1.[CH3:33][CH2:32][C:17]([N+:14]([O-:16])=[O:15])([CH2:25][N:26]1[CH2:27][CH2:28][O:29][CH2:30][CH2:31]1)[CH2:18][N:19]1[CH2:24][CH2:23][O:22][CH2:21][CH2:20]1

Participants

3

Reactant 2

HCID 612794,4'-(2-Ethyl-2-nitrotrimethylene)dimorpholineHCID 624404-(2-Nitrobutyl)morpholine

Product 1

HCID 916224-(2-Nitrobutyl)morpholine - 4,4'-(2-ethyl-nitrotrimethylene)dimorpholine mixture

Procedure

The product contained 88.95% of 4-(2-nitrobutyl)-morpholine and 3.85% 4,4'-(2-nitro-2-ethyltrimethylene)-dimorpholine. The P-1487 product produced when screened for eye irritation properties was found to be non-lachrymatory.

Sources & evidence

ORD record
ord-66e2740305fd4f638d2402745e672730
Source dataset
uspto-grants-1978_05
Patent number
US04088817

Reaction notes

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