[o-(3-Chloro-o-toluidino)-phenyl]-acetohydroxamic acid → [o-(2,6-Dichloroanilino)-phenyl]-acetohydroxamic acid

HRID 372847Notes

Reaction equation

HRID 372847 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4](C)[C:3]=1[NH:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=1[CH2:16][C:17]([NH:19][OH:20])=[O:18].[N+](C1C=CC(OC(=O)CC2C=CC=CC=2NC2C(C)=CC=CC=2[Cl:46])=CC=1)([O-])=O>>[Cl:46][C:4]1[CH:5]=[CH:6][CH:7]=[C:2]([Cl:1])[C:3]=1[NH:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=1[CH2:16][C:17]([NH:19][OH:20])=[O:18]

Participants

3

Reactant 2

HCID 20387094[o-(3-Chloro-o-toluidino)-phenyl]-acetohydroxamic acidHCID 70610970HCID 70610970, compound

Product 1

HCID 20300230[o-(2,6-Dichloroanilino)-phenyl]-acetohydroxamic acid

Procedure

[o-(3-chloro-o-toluidino)-phenyl]-acetohydroxamic acid, M.P. 135° - 136° (from ether/petroleum ether), starting with [o-(3-chloro-o-toluidino)-phenyl]-acetic acid-p-nitrophenyl ester.

Sources & evidence

ORD record
ord-606a74a0061141b09c96e78f52e16dcb
Source dataset
uspto-grants-1978_05
Patent number
US04092430

Reaction notes

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