Acrylic Acid → 2-Hydroxy-3-phenoxypropyl prop-2-enoate

HRID 372850Notes

Reaction equation

HRID 372850 reaction equation
[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3].C([C:10]1[C:15]([OH:16])=[C:14](C(C)(C)C)[CH:13]=[C:12](C)[CH:11]=1)(C)(C)C>>[C:1]([O:5][CH2:14][CH:15]([OH:16])[CH2:10][O:16][C:15]1[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1)(=[O:4])[CH:2]=[CH2:3]

Participants

3

Reactant 2

HCID 6581Acrylic Acid2×HCID 314042,6-Di-tert-butyl-4-methylphenol

Product 1

HCID 44435162-Hydroxy-3-phenoxypropyl prop-2-enoate

Procedure

3-Phenoxy-2-hydroxypropyl acrylate was prepared as described in Example 17 except that the acrylic acid was added over 1 hour at 100°, 2,6-di-tert. butyl-p-cresol was used in place of hydroquinone, and the mixture was heated for 4 hours at 100° after the acrylic acid had been added.

Workup

  1. additionwas added over 1 hour at 100°
  2. additionhad been added

Sources & evidence

ORD record
ord-388e24edfcad4ae1a4d07262f234e828
Source dataset
uspto-grants-1978_05
Patent number
US04092443

Reaction notes

Loading…