Oxygen → 1-Tetralone

HRID 372944Notes

Reaction equation

HRID 372944 reaction equation
[CH2:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH2:4][CH2:3][CH2:2]1.[O:11]=O>O>[CH2:7]1[CH:8]([OH:11])[CH2:9][C:10]2[C:5](=[CH:4][CH:3]=[CH:2][CH:1]=2)[CH2:6]1.[C:9]1(=[O:11])[C:10]2[C:5](=[CH:4][CH:3]=[CH:2][CH:1]=2)[CH2:6][CH2:7][CH2:8]1

Participants

5

Reactant 2

HCID 977OxygenHCID 8404Tetralin

Product 2

HCID 107241-TetraloneHCID 107471,2,3,4-Tetrahydro-2-naphthalenol

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

The thus-obtained metal complex (1.5 mM) was dispersed as a catalyst in water. Tetralin (15 mM) was dispersed therein as a reaction substrate, and the mixture was shaked in an atmosphere of oxygen at 1 atmospheric pressure to produce tetralol and tetralone. After 24 hours, concentration of tetralin was decreased to 30 % or less based on the initial concentration.

Sources & evidence

ORD record
ord-f747424651424357ad382601e61c92d7
Source dataset
uspto-grants-1992_11
Patent number
US05162279

Reaction notes

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