HuagongsheHuagongshe Chemistry Print Report · For research reference only
Oxygen → Bicyclo(2.2.1)heptan-2-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Oxygen | HCID 977 | — |
| Reactant | 2-Norbornene | HCID 10352 | — |
| Product | Bicyclo(2.2.1)heptan-2-one | HCID 10345 | 70% |
| Product | 1-Cyclohexene-1-carboxaldehyde | HCID 5184540 | 30% |
Reaction Steps
7.1 g norbornene and 1 atm O2 were passed over 100 mg of this material at 280° C. for 2 hours, yielding in a partial conversion 99 mg norbornanone (relative yield 70%) and 43 mg cyclohexene carboxaldehyde (relative yield 30%) with a turnover frequency of 160 moles total product per mole Rh per hr.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05162285 |
| Source dataset | uspto-grants-1992_11 |
| ORD ID | ord-4bb6ecef8ce947c0a9f2a7776e14e54b |
| Source note | uspto-grants-1992_11 |