HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-(4-Octyloxyphenyl)benzoyl chloride → 4-(2-Pentanoyloxy-1-keto-propyl)-phenyl 4'-octyloxybiphenyl-4-ylcarboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-(4-Octyloxyphenyl)benzoyl chloride | HCID 11078473 | — |
| Reactant | 1-Methyl-2-(4'-allyloxy-phenyl)-2-keto-ethyl 4'-heptylbiphenyl-4-ylcarboxylate | HCID 19810057 | — |
| Reactant | 4-(2-Pentanoyloxy-1-keto-propyl)phenol | HCID 19810129 | — |
| Catalyst | 4-(Dimethylamino)pyridine | HCID 14284 | — |
| Product | 4-(2-Pentanoyloxy-1-keto-propyl)-phenyl 4'-octyloxybiphenyl-4-ylcarboxylate | HCID 19810040 | — |
Reaction Steps
A mixture of 500 mg of 4'-octyloxy-biphenyl-4-yl-carboxylic acid chloride, 400 mg of (S) 4-(2-pentanoyloxy-1-keto-propyl)phenol, 600 mg of N,N-dicyclohexylcarbodiimide, and 20 mg of DMAP was stirred at room temperature for three hours. A solid material precipitated was removed by filtration. The organic layer thus obtained was washed with an acid, an alkali, and with water, dried, and then concentrated.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05164112 |
| Source dataset | uspto-grants-1992_11 |
| ORD ID | ord-af6d64d2a7ba4b25a4acd3588fc4cde5 |
| Source note | uspto-grants-1992_11 |