HCID 67653663, compound → Morpholine, 4-(2-methoxyethyl)-

HRID 373668Notes

Reaction equation

HRID 373668 reaction equation
[CH3:1][O:2][C:3](=O)O.OC[CH2:8][N:9]1[CH2:14][CH2:13][O:12][CH2:11][CH2:10]1>C1CCCCC1>[CH3:13][O:12][CH2:11][CH2:10][N:9]1[CH2:14][CH2:1][O:2][CH2:3][CH2:8]1

Participants

3

Reactant 1

HCID 67653663HCID 67653663, compound

Product 1

HCID 82460Morpholine, 4-(2-methoxyethyl)-

Reagents, catalysts & solvents 1

HCID 8078CyclohexaneSolvent

Procedure

Using the apparatus employed in Examples 5-27, a 20 percent (volume) solution of 4-(2-hydroxyethyl)morpholine methyl carbonate prepared in Example 30 in cyclohexane was passed through 6.0 grams of Catalyst J at a temperature of 300° C. and a liquid feed rate of 0.27 milliliters per minute. A total of 7.4 grams of product was recovered. Capillary gas chromatographic analysis (area percent) of this material showed 67.7 percent selectivity to 4-(2-methoxyethyl)morpholine at 100 percent 4-(2-hydroxyethyl)morpholine methyl carbonate conversion.

Workup

  1. customA total of 7.4 grams of product was recovered

Sources & evidence

ORD record
ord-45aa2d7a3bf34e14bfc9df12681b740c
Source dataset
uspto-grants-1992_11
Patent number
US05164497

Reaction notes

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