HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Ethylhexanal → 5-Amino-5-hydroxymethyl-2-(3-heptyl)-1,3-dioxane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Ethylhexanal | HCID 31241 | — |
| Reactant | Tris(hydroxymethyl)nitromethane | HCID 31337 | — |
| Product | 5-Amino-5-hydroxymethyl-2-(3-heptyl)-1,3-dioxane | HCID 18996049 | 95.1% |
Reaction Steps
Procedure of Example 2 was repeated with 6.41 g of 2-ethylhexanal and 7.56 g of 2-(hydroxymethyl)-2-nitro-1,3-propanediol to give 11 g of 5-nitro-5-hydroxymethyl-1,3-dioxane derivative, which was reduced and distilled at 175°-178° C. to give 8.7 g of the product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05482965 |
| Source dataset | uspto-grants-1996_01 |
| ORD ID | ord-3a82a3418c454d79b570a00b1fb4f332 |
| Source note | uspto-grants-1996_01 |