HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diiodomethane → HCID 18996357, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diiodomethane | HCID 6346 | — |
| Reactant | 3-(Trifluoromethoxy)benzaldehyde | HCID 605139 | — |
| Catalyst | Titanium isopropoxide | HCID 11026 | — |
| Catalyst | Zinc | HCID 23994 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 18996357 | HCID 18996357 | — |
Reaction Steps
A solution of one mole equivalent of m-trifluoromethoxybenzaldehyde in dry tetrahydrofuran is combined with 5 mole equivalents of diiodomethane, 9 mole equivalents of zinc powder, 1 mole equivalent of titanium tetraisopropoxide, and the mixture is stirred at room temperature for 3 hours. The product is extracted from the mixture after removal of solvent in vacuo to give m-trifluoromethoxyphenylethene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05482971 |
| Source dataset | uspto-grants-1996_01 |
| ORD ID | ord-9859bf8648b8439992e5d609e553e5cc |
| Source note | uspto-grants-1996_01 |