HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hexylbenzene → 4'-n-Hexylbenzoin
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hexylbenzene | HCID 14109 | — |
| Reactant | Glyoxal, phenyl-, hydrate | HCID 12215922 | — |
| Catalyst | Titanium Tetrachloride | HCID 24193 | — |
| Solvent | 1,1-Dichloroethane | HCID 6365 | — |
| Product | 4'-n-Hexylbenzoin | HCID 23513069 | — |
Reaction Steps
Phenylglyoxal monohydrate (304 mg, 2 mM) and n-hexylbenzene (0.76 ml, 4 mM) were dissolved in dichloroethane (3 ml), titanium tetrachloride (0.33 ml, 3 mM) was added, and reacted at room temperature for 1 hour. Using the same procedure as in Example 1, 4'-n-hexylbenzoin was obtained as crystal (352.8 mg, 59.4% yield).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05484689 |
| Source dataset | uspto-grants-1996_01 |
| ORD ID | ord-d0629f092da5423c9442b00eb2dd7720 |
| Source note | uspto-grants-1996_01 |