HuagongsheHuagongshe Chemistry Print Report · For research reference only
M-Xylene → HCID 18994048, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | M-Xylene | HCID 7929 | — |
| Reactant | Glyoxal, phenyl-, hydrate | HCID 12215922 | — |
| Catalyst | Titanium Tetrachloride | HCID 24193 | — |
| Solvent | 1,1-Dichloroethane | HCID 6365 | — |
| Product | HCID 18994048 | HCID 18994048 | — |
Reaction Steps
Phenylglyoxal monohydrate (304 mg, 2 mM) and m-xylene (0.49 ml, 4 mM) were dissolved in dichloroethane (4 ml), titanium tetrachloride (0.33 ml, 3 mM) was added, and reacted at room temperature for 30 minutes. Using the same procedure as in Example 1, 3', 5'-dimethylbenzoin was obtained as a light-yellow oil (363.2 mg, 75.3% yield).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05484689 |
| Source dataset | uspto-grants-1996_01 |
| ORD ID | ord-6585b0686e04428b90da97ed41662992 |
| Source note | uspto-grants-1996_01 |