HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diphenyl Ether → HCID 23513118, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diphenyl Ether | HCID 7583 | — |
| Reactant | Glyoxal, phenyl-, hydrate | HCID 12215922 | — |
| Catalyst | Titanium Tetrachloride | HCID 24193 | — |
| Solvent | 1,1-Dichloroethane | HCID 6365 | — |
| Product | HCID 23513118 | HCID 23513118 | — |
Reaction Steps
Phenyglyoxal monohydrate (200 mg, 1.31 mM) and diphenylether (0.4 ml, 2.62 mM) were dissolved in dichloroethane (3 ml), titanium tetrachloride (0.07 ml, 0.66 mM) was added, and reacted at room temperature for 1 hour. Using the same procedure as in Example 1, 4'-phenoxybenzoin was obtained as crystal (331.2 mg, 80.7% yield).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05484689 |
| Source dataset | uspto-grants-1996_01 |
| ORD ID | ord-11b1c106ec8946fc89106d710e488c94 |
| Source note | uspto-grants-1996_01 |