Carbon Dioxide → Barium Carbonate

HRID 376821Notes

Reaction equation

HRID 376821 reaction equation
[OH-:1].[Ba+2:2].[OH-].[C:4](=[O:6])=[O:5].[I:7]([O-:11])(=[O:10])(=[O:9])=[O:8].[Na+]>>[I:7]([O-:10])(=[O:9])=[O:8].[Ba+2:2].[I:7]([O-:10])(=[O:9])=[O:8].[I:7]([O-:11])(=[O:10])(=[O:9])=[O:8].[Ba+2:2].[I:7]([O-:11])(=[O:10])(=[O:9])=[O:8].[C:4](=[O:1])([O-:6])[O-:5].[Ba+2:2]

Participants

6

Reactant 3

HCID 280Carbon DioxideHCID 6093286Barium hydroxideHCID 23667635Sodium periodate

Product 3

HCID 10563Barium CarbonateHCID 165892Barium iodateHCID 16217315Barium periodate

Procedure

The diol 16-mer (1 nmol.) is dissolved in sodium metaperiodate solution (20 ul, 20 mM, pH 4.5) and allowed to stand at room temperature for 30 min. Barium hydroxide (3.3 ul of a 150 mM solution) is added and the solution cooled on ice for 5 min. A small crystal of dry ice is then added and the solution is vortexed and centrifuged. The supernatant (22 ul) containing aldehyde 16-mer is removed, leaving behind the precipitate of barium iodate, barium periodate, and barium carbonate.

Workup

  1. temperaturethe solution cooled on ice for 5 min
  2. customis removed

Sources & evidence

ORD record
ord-ab18c8b6d3b34aa8be7639cfbf995101
Source dataset
uspto-grants-2000_02
Patent number
US06022714

Reaction notes

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